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  • Iron(II) chloride, also known as ferrous chloride, is the chemical compound of formula FeCl2.
  • It has a high melting point, paramagnetic solid, usually obtained as an off-white solid.


  • FeCl2 prepared in this way exhibits convenient solubility in tetrahydrofuran, a common solvent for chemical reactions.
  • In one of two classic syntheses of ferrocene, Wilkinson generated FeCl2 by heating FeCl3 with iron powder.
  • Ferric chloride decomposes to ferrous chloride at high temperatures.


  • To introducing chlorine gas to ferrous chloride, it is possible to regenerate ferric chloride.
  • The NJME Pollution Prevention team needed to determine how much chlorine gas was needed to convert the company’s 49,997 lbs of ferrous into ferric chloride.


  • Ferrous chloride has a variety of niche applications, but the related compounds ferrous sulfate and ferric chloride enjoy more applications.
  • Aside from use in the laboratory synthesis of iron complexes, ferrous chloride serves as a reducing flocculating agent in wastewater treatment, especially for wastes containing chromate.

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