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Cofacial Polymers

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  • Cofacial polymers are Metallophthalocyanine polymers ([M(Pc)O]n) where M=Si,Ge or Sn then Pc=Phthalocyanine, Silicon (germanium) oxo hemiporphyrazine polymers([M(hp)O]n).

  • The solubility of the Lewis acid complexes of metallophthalocyanines and pi-conjugated polymers in a common organic solvent has allowed us to prepare well-defined supramolecular materials which combine the electro active and photoactive properties of both components.

  • The resulting composites have excellent optical transparency and enhanced photoconductivity.

  • Major applications of these types of polymers are electrical conductors, semiconductors and materials with photopotical properties.

  • Polymeric metallophthalocyanines are expected to possess electronic conductivity, electro catalytic properties and to offer efficient corrosion protection to metal surfaces.

  • The present study intends to investigate the possibility to obtain a polymeric
    metallophthalocyanines via electrochemical polymerization.

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