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  • Sodium fluoride is the chemical compound with the formula NaF.
  • This colourless solid is the main source of the fluoride ion in diverse applications.
  • The mineral form of NaF, villiaumite, is moderately rare. It is known from plutonic nepheline syenite rocks.
  • Sodium Fluoride is prepared by neutralizing waste hydrofluoric acid resulting from the production of super phosphate fertilizer.


  • Sodium fluoride is used in laundry souring, manufacturing enamels, manufacturing coated papers, wood preservative , foam production, opal glass, ore flotation and water fluoridation.
  • Sodium fluoride is used as a cleaning agent, often to remove iron stains.
  • It is a reagent for the synthesis of fluorocarbons.


  • Due to its efficacy in caries prophylaxis and easy application, sodium fluoride is still used for caries prevention in the form of fluoridated drinking water, fluoride tablets, fluoridated salt or milk.
  • Hydrofluoric acid is quite weak and even the organic acids can decompose sodium fluoride with the production of hydrofluoric acid.
  • In the US, NaF was once used to fluoridate drinking water but its use has been displaced by hexafluorosilicic acid or the related sodium salt.

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